From the Latin alumen, meaning “bitter salt”, the Alum Stone was already mentioned in the famous work of Dioscorides, De Materia Medica. It has been used since Antiquity for its numerous properties, the main of which is its astringent power. Tightening pores, it is a real natural daily ally to limit perspiration and reduce the dilation of pores in problem skin. It also facilitates the healing of small wounds linked to acne or hair removal and shaving. Denigrated in recent years because of the dangers mentioned of aluminum salts in deodorants, we tell you everything about this surprising stone.

This article was updated on 29/08/2023

What is Alum Stone?

Alum Stone is actually a crystal extracted from a mineral called alunite or bauxite. At the time, the latter came from Syrian quarries but today it is present in mines, surface outcrops or volcanic soils all over the world. This mineral is a double sulfate of aluminum and potassium. In natural cosmetics, alum stone is used for different benefits. First of all for its astringent nature which means that it tightens the pores of the skin. This characteristic allows it to regulate perspiration and to be used as an antiperspirant and natural deodorant but it also reduces the deposition of sebum in oily skin. Thanks to this property, the stone also facilitates healing, it is often used following hair removal or shaving to stop micro-bleeding and soothe the skin.

You can find the Alum Stone in two forms:

  • In block: Once purified, the potassium alum crystals are recrystallized in the form of a block or stick that can be used directly on the skin.

  • In powder: The crystals are then ground into a very fine powder which will be incorporated into your homemade cosmetic preparations for the same properties.

Respectful of your skin and the environment, it is an ideal alternative to commercial deodorants. Without aluminum chlorohydrates, perfume, silicones, preservatives or propellant gases destroying the ozone layer, Alum Stone is your ally in natural cosmetics. Simple, quick to use and also advantageous from an economic point of view, the latter can be used for years without losing its effectiveness, knowing that a single 100 g stick is equivalent to the use of around ten conventional spray deodorants.

How to use the Alum Stone?

In cosmetics

To benefit from the benefits of natural alum stone, simply moisten it with water before use. Then apply it to dry, healthy skin. Depending on the properties sought, you can use it in combination with essential oils or floral waters to optimize its benefits. Here are some ideas:

  • Natural deodorant 

Using alum stone with hydrosols or essential oils can effectively regulate perspiration as well as limit the small inconveniences with which it is associated.

- Essential oils : Rosat Geranium, Fine Lavender, Palmarosa, Clary Sage, Peppermint, Provence Cypress. Add a drop of essential oil with antibacterial properties and a pleasant scent to your stone to additionally act on perspiration odors.

- Hydrosols : Peppermint, Clary Sage. Moisten your stone with these hydrosols to regulate the hormones responsible for perspiration and provide a refreshing sensation.

  • Oily and acne-prone skin 

Given its astringent and therefore mattifying nature, alum stone is appreciated by oily and acne-prone skin to tighten enlarged pores collecting sebum.

- Essential oils : Tea Tree, Rosat Geranium, Petit grain of Bigarade, Fine Lavender. Add a drop of essential oil with purifying and anti-inflammatory properties to your stone to reduce your acne spots.

- Hydrosols : Peppermint, Rosemary Verbenone, Witch Hazel, Cistus, Tea Tree. Moisten your stone with these hydrosols to reduce the shine in certain areas of your face.

  • Healing

The astringent property of alum stone also allows it to accelerate the healing process, even more so with appropriate essential oils and hydrosols.

- Essential oils : Italian Helichrysum, True Lavender, Rosat Geranium. Add a drop of healing and purifying essential oil to your stone to regenerate skin cells and reduce scars.

- Hydrosols : Rosat Geranium, Italian Helichrysum, Yarrow, Cistus. Moisten your stone with these hydrosols to complete the healing action on damaged skin.

Technical sheet of alum stone

Main properties

Astringent : Alum stone is an astringent mineral, which means that it will tighten the pores of the skin. It is through this property that it helps to limit perspiration in a natural way. It is also an ally for oily and acne-prone skin with enlarged pores.

Healing : Alum stone therefore has, thanks to its astringency, the ability to accelerate the healing process using the thin mineral layer deposited on the surface of the skin.

Hemostatic : Alum stone helps stop micro-bleeding which can occur, particularly after micro-cuts due to hair removal or shaving.

Technical characteristics

Biochemical characteristics

A good natural alum stone must contain (in %) :

  • SO3 : 34 %
  • Al2O3 : 11 %
  • K2O : 10 %
  • H2O : 45 %
Physical characteristics

A good natural alum stone should have the following physical characteristics:

  • Density at 20°C: 1.75
  • pH: 3.5 (+/- 0.5)
  • Melting point: + 92° C
Organoleptic characteristics

What a good natural alum stone looks like:

  • Appearance: crystal block or fine powder
  • Color: translucent, whitish
  • Odor: odorless

Precautions for using alum stone

Authorized ways of use
Authorized users
Attention

Do not use on damaged skin. Avoid contact with mucous membranes.

Storage and preservation

Allow to dry after use. Store away from humidity, light and heat.

Does Alum Stone present any dangers?

Aluminum

Aluminum is one of the most abundant natural elements in the earth's crust and which in very high doses in the bloodstream can be dangerous for human health. Recently, aluminum salts have been singled out for their increased presence in consumer products: water, food, medicines and cosmetic products. Like other chemical compounds, they would have an impact on the development of various neurological and cancerous pathologies.

Within cosmetic products, these are more precisely the aluminum chlorohydrates mostly found in commercial deodorants and antiperspirants which are blamed for their carcinogenic nature. They would facilitate the passage of aluminum into the body through the skin. However, no official study has determined whether or not aluminum passes through the skin. The National Agency for the Safety of Medicines and Health Products (formerly Afssaps) has assessed the risks to which cosmetic consumers are exposed when faced with different types of aluminum salts. This study did not demonstrate a link between aluminum and cancer but as a precaution, it was still decided to restrict the quantity of aluminum to 0,6 % in cosmetic products. It is also not recommended to use products containing aluminum on damaged skin in order to avoid any passage into the blood.

There Natural alum stone does not contain aluminum chlorohydrates and no official remark, study or fact has concluded that there is any toxicity on its part under reasonable conditions of use.

Natural stone VS Synthetic stone

And yes, you have to be careful when you get alum stone because there is a natural one and another synthetic one. They differ in their manufacturing processes and chemical composition.
Stone
natural is therefore alum potassium extracted from alunite which will be purified then recrystallized by natural methods over a period of approximately 6 months. The Alum Stone synthetic as for it is obtained by heavy polluting chemical processes. It is composed ofalum ammonium (N.H.4)Al(SO4)2 from residues and ammonium salts, the majority of which comes from the nylon industry in Asia. The use of the latter has repeatedly reported irritation and inflammation in the armpits among consumers. So be careful and once again favor Mother Nature!

The manufacture of natural alum stone

To make your natural alum stone stick, the extracted alunite will undergo four operations:

  • there calcination : This step is carried out over one day and under very high temperature, between 600 and 700°C. It allows all the water to be lost from the ore in order to obtain anhydrous sulfate as well as alumina. It is very important to control the temperature during this stage because below 600°C the decomposition of the alunite is incomplete and above 700°C the sulfates are lost but they are necessary for the formation of the stone.

  • there maceration : Then the anhydrous sulfate obtained is rehydrated during maceration by watering with water to form potassium alum of formula KAl(SO4)2•12H2O. This stage is the longest and can last 2 to 4 months maximum until a pasty mass is obtained from which the alum potassium will be extracted.

  • there leaching : This operation makes it possible to extract the potassium from alum following maceration. It consists of leaching the pasty mineral mass in hot or even boiling water in order to solubilize the alum and remove the impurities which are insoluble. This also aims to concentrate the alum potassium before its crystallization.

  • there crystallization : This is the last step in making your stick. The hot solution of potassium alum previously recovered is placed in tanks in which it will cool over a fortnight to form crystals. Those placed in the center of the tanks are then recovered to be cut and polished according to the desired shape.

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